You are not logged in Total: 7journals, 20,687articles Online
Login / Register
Forgot Login?
Main menuMain menu
What's new
Journal list
Visiting ranking
Phrase ranking
About us
Journal Site
Advanced Search

Home  >  Journal list  >  Journal of the Ceramic Society of Japan  >  Vol.121  No.1416 (August) (2013)  >  pp.583-588

Journal of the Ceramic Society of Japan
<<Previous article Vol.121  No.1416 (August) (2013)   pp.583 - 588 Next article>>

Characterization of BaTiO3 crystals formed in aluminosilicate glasses and their laser patterning

Takayuki KOMATSU1), Takashi OIKAWA1), Tsuyoshi HONMA1)
1) Department of Materials Science and Technology, Nagaoka University of Technology

BaTiO3 crystals synthesized through the crystallization of 40BaO–40TiO2–15SiO2–5Al2O3 glass were characterized from Raman scattering spectrum, second harmonic generation (SHG), and polarization measurements. The structure of BaTiO3 nanocrystals (~70 nm) formed initially was suggested to be pseudo-cubic (small tetragonality), and perovskite-type ferroelectric BaTiO3 crystals were formed in the heat-treatments at high temperatures of ~930°C. The lines consisting of BaTiO3 crystals were patterned at the surface of CuO-doped glass by irradiations of continuous-wave Yb:YVO4 lasers with a wavelength of 1080 nm. It was confirmed that BaTiO3 being present in the laser-irradiated parts exhibits SHGs and, in particular, BaTiO3 formed in the laser ablation region has a tetragonal structure and a Curie temperature of ~135°C.

BaTiO3, Glass, Crystallization, Raman scattering spectrum, Second harmonic generation, Laser pattering

Received: March 01, 2013
Accepted: April 12, 2013 , Published online: August 01, 2013
Copyright © 2013 The Ceramic Society of Japan



Terms of Use | Privacy Policy