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Home  >  Journal list  >  Journal of the Ceramic Society of Japan  >  Vol.123  No.1441 (September) (2015)  >  pp.813-815

Journal of the Ceramic Society of Japan
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A direct synthesis of the styrylimido derivative of the hexamolybdate dianion

Jeffrey FISCHER1), Tiffany STAMPKA1), Mark F. ROLL1)
1) Department of Chemical & Materials Engineering, The University of Idaho

Polyoxometalate imides represent an area of materials chemistry research that recently has seen exciting exploration. Consisting of polyhedral metal-oxide clusters covalently coupled to organic ligands, they possess a combination of electrochemical activity and poly-anionic character hint. These characteristics suggest significant opportunities in the area solid-electrolytes, particularly if the typically good film forming characteristics of hybrid polymers can be accessed. The incorporation of a styryl group allows for hybrid polymers to be synthesized through free radical methods, producing hybrid materials that offer that an enormous number of opportunities to both materials scientists and engineers. This Note will document a concise route to quickly produce the readily polymerizable, styrylimido-hexamolybdate monomer from low cost precursor materials by leveraging recent advances and address some of the synthetic challenges found.

Polyoxometalate, Hybrid polymer

Received: March 31, 2015
Accepted: June 08, 2015 , Published online: September 01, 2015



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