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Home  >  Journal list  >  Journal of the Ceramic Society of Japan  >  Vol.122  No.1426 (June) (2014)  >  pp.520-522

Journal of the Ceramic Society of Japan
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A relationship between oxidation state of iron and color of Arita celadon glaze characterized by 57Fe-Mössbauer spectroscopy

Hiroaki KATSUKI1), Atsunori SHIRAISHI1), Jae-Hwan PEE2), Woo-Seok CHO2), Yusuke TAKAHASHI3), Shiro KUBUKI3)
1) Saga Ceramics Research Laboratory 2) Icheon Branch, Korea Institute of Ceramic Engineering and Technology 3) Department of Chemistry, Graduate School of Science and Engineering, Tokyo Metropolitan University

The effect of firing atmosphere on the oxidation states of Fe in Arita celadon glaze and the glaze color was examined by using Mössbauer spectroscopy. The celadon glaze was prepared from feldspar, BaCO3, kaolin, α-quartz, and Fe2O3 powders and fired on the white porcelain biscuit plate at 1300°C for 0.5 h under several reduction atmospheres. The content of Fe2O3 in the glaze was 2 mass %. In oxygen atmosphere, the color of celadon glaze was gray-yellow due to Fe3+. The color of the celadon glaze changed from gray-yellow to blue-green with increase of CO concentration in the atmosphere. With the increase CO concentration, Fe2+ increased and the concentrations of Fe2+ were 85.9% at 0.5%CO and 95.6% at 1%CO, respectively. At 4% CO, iron state was only Fe2+.

Arita celadon, Oxidation states of Iron, Color, 57Fe-Mössbauer spectroscopy

Received: February 13, 2014
Accepted: March 22, 2014 , Published online: June 01, 2014
Copyright © 2014 The Ceramic Society of Japan



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